IS 12679:1989 specifies the requirements and testing methods for by-product gypsum used in the manufacture of plaster, blocks, and boards. It covers chemical composition limits, sampling procedures, packing, and marking requirements for phosphogypsum, fluorogypsum, and marine gypsum by-products. This standard is essential for manufacturers, quality controllers, and engineers involved in construction materials to ensure the safe and effective utilization of by-product gypsum in building applications.
Overview
IS 12679:1989 specifies the requirements and testing methods for by-product gypsum used in the manufacture of plaster, blocks, and boards. It covers chemical composition limits, sampling procedures, packing, and marking requirements for phosphogypsum, fluorogypsum, and marine gypsum by-products. This standard is essential for manufacturers, quality controllers, and engineers involved in construction materials to ensure the safe and effective utilization of by-product gypsum in building applications.
Audience
Contents
Structure
Scope:
IS 12679 covers By-Product Gypsum used in construction, specifying chemical requirements and testing methods to ensure quality.
| Characteristic | Phospho-Gypsum | Fluoro-Gypsum | Marine Gypsum | Test Reference |
|---|---|---|---|---|
| P₂O₅, % by mass, Max | 0.40 | - | - | IS 6361 : 1971 |
| F, % by mass, Max | 0.40 | 1.0 | - | IS 2411 : 1963 |
| Na₂O, % by mass, Max | 0.10 | - | - | IS 9497 : 1980 |
| K₂O, % by mass, Max | 0.20 | - | - | IS 9497 : 1980 |
| Organic matter, % by mass, Max | 0.15 | - | - | IS 2720 (Part 22):72 |
| CaSO₄·2H₂O, % by mass, Min | 85.0 | 90.0 | 85.0 | IS 1288 : 1982 |
| Cl as NaCl, % by mass, Max | 0.10 | - | 0.10 | IS 1288 : 1982 |
| pH (10% aqueous suspension), Min | 5.0 | 5.0 | 6.0 | IS 5741 : 1970 |
| Lot Size (No. of Packages) | No. of Packages to Sample |
|---|---|
| Up to 100 | 3 |
| 101 to 150 | 4 |
| 151 to 300 | 5 |
| 301 to 500 | 7 |
| 501 and above |
IS 12679 Key References and Specifications
| Characteristic | Phospho-gypsum | Fluoro-gypsum | Marine gypsum | Test Reference |
|---|---|---|---|---|
| P2O5, % mass, Max | 0.40 | - | - | IS 6361:1971 |
| F, % mass, Max | 0.40 | 1.0 | - | IS 2411:1963 |
| Na2O, % mass, Max | 0.10 | - | - | IS 9497:1980 |
| K2O, % mass, Max | 0.20 | - | - | IS 9497:1980 |
| Organic matter, % mass, Max | 0.15 | - | - | IS 2720 (Part 22):1972 |
| CaSO4·2H2O, % mass, Min | 85.0 | 90.0 (Note 2) | 85.0 | IS 1288:1982 |
| Cl as NaCl, % mass, Max | 0.10 | - | 0.10 | IS 1288:1982 |
| pH (10% aqueous suspension) Min | 5.0 | 5.0 | 6.0 | IS 5741:1970 |
Note: Impurities above limits require processing.
| Lot Size (No. of Packages) | No. of Packages to Sample |
|---|---|
| Up to 100 | 3 |
| 101 to 150 | 4 |
| 151 to 300 | 5 |
| 301 to 500 | 7 |
| 501 |
IS 12679 - Chemical Requirements for By-Product Gypsum
| Characteristic | Phospho-gypsum | Fluoro-gypsum | Marine gypsum | Test Method Reference |
|---|---|---|---|---|
| P₂O₅, % by mass, Max | 0.40 | - | - | IS 6361 : 1971 |
| F, % by mass, Max | 0.40 | 1.0 | - | IS 2411 : 1963 |
| Na₂O, % by mass, Max | 0.10 | - | - | IS 9497 : 1980 |
| K₂O, % by mass, Max | 0.20 | - | - | IS 9497 : 1980 |
| Organic matter, % by mass, Max | 0.15 | - | - | IS 2720 (Part 22) : 1972 |
| CaSO₄·2H₂O, % by mass, Min | 85.0 | 90.0 (Note 2) | 85.0 | IS 1288 : 1982 |
| Cl as NaCl, % by mass, Max | 0.10 | - | 0.10 | IS 1288 : 1982 |
| pH of 10% aqueous suspension, Min | 5.0 | 5.0 | 6.0 | IS 5741 : 1970 |
This ensures by-product gypsum quality for safe and effective use in construction
IS 12679 - Sampling: Key Formulas, Tables, and Specifications
| Lot Size (No. of Packages) | No. of Packages to be Sampled |
|---|---|
| Up to 100 | 3 |
| 101 to 150 | 4 |
| 151 to 300 | 5 |
| 301 to 500 | 7 |
| 501 and above | 10 |
flowchart LR
A[Start: Lot Size Known] --> B{Lot Size?}
B -->|Up to 100| C[Select 3 Packages]
B -->|101-150| D[Select 4 Packages]
B -->|151-300| E[Select 5 Packages]
B -->|301-500| F[Select 7 Packages]
B -->|501+| G[Select 10 Packages]
C & D & E & F & G --> H[Select Randomly per IS 4905]
H --> I[Conduct Tests]
I --> J[Round Results per IS 2]
This ensures statistically valid sampling and consistent test reporting.
IS 12679: Packing and Marking - Key Points
| Lot Size (No. of Packages) | No. of Packages to Sample |
|---|---|
| Up to 100 | 3 |
| 101 to 150 | 4 |
| 151 to 300 | 5 |
| 301 to 500 | 7 |
| 501 and above | 10 |
flowchart TD
A[By-product Gypsum] --> B[Pack in Bags/Containers]
B --> C[Mark Package]
C --> D[Name & Manufacturer]
C --> E[Date of Manufacture]
C --> F[Standard Mark (BIS)]
F --> G[Quality Assurance & Inspection]
This ensures traceability, quality, and compliance with IS 12679.
IS 12679 - Criteria for Conformity (Clause 4.4)
| Lot Size (No. of Packages) | Sample Size (No. of Packages) |
|---|---|
| Up to 50 | 5 |
| 51 to 100 | 8 |
| 101 to 500 | 13 |
| Above 500 | 20 |
flowchart TD
A[Lot of Packages] --> B[Random Sampling per IS 4905]
B --> C[Composite Sample]
C --> D{Test Results}
D -->|Meets Requirements| E[Conformity Confirmed]
D -->|Fails Any Test| F[Non-Conformity]
This ensures quality control by statistically verifying compliance through representative sampling and standardized testing.
Rounding Off:
| Characteristic | Phospho-Gypsum | Fluoro-Gypsum | Marine Gypsum | Test Method Reference |
|---|---|---|---|---|
| P2O5, % by mass, Max | 0.40 | - | - | IS 6361:1971 |
| F, % by mass, Max | 0.40 | 1.0 | - | IS 2411:1963 |
| Na2O, % by mass, Max | 0.10 | - | - | IS 9497:1980 |
| K2O, % by mass, Max | 0.20 | - | - | IS 9497:1980 |
| Organic matter, % by mass, Max | 0.15 | - | - | IS 2720 (Part 22):1972 |
| CaSO4·2H2O, % by mass, Min | 85.0 | 90.0 | 85.0 | IS 1288:1982 |
| Cl as NaCl, % by mass, Max | 0.10 | - | 0.10 | IS 1288:1982 |
| pH (10% aqueous suspension), Min | 5.0 | 5.0 | 6.0 | IS 5741:1970 |
flowchart
IS 12679: Key Notes, Annexures, and Tables
| Lot Size (No. of Packages) | No. of Packages to Sample |
|---|---|
| Up to 100 | 3 |
| 101 to 150 | 4 |
| 151 to 300 | 5 |
| 301 to 500 | 7 |
| 501 and above | 10 |
| Characteristic | Phospho-gypsum | Fluoro-gypsum | Marine gypsum | Test Reference |
|---|---|---|---|---|
| P₂O₅, % by mass, Max | 0.40 | - | - | IS 6361 : 1971 |
| F, % by mass, Max | 0.40 | 1.0 | - | IS 2411 : 1963 |
| Na₂O, % by mass, Max | 0.10 | - | - | IS 9497 : 1980 |
| K₂O, % by mass, Max | 0.20 | - | - | IS 9497 : 1980 |
| Organic matter, % by mass, Max | 0.15 | - | - | IS 2720 (Part 22):1972 |
| CaSO₄·2H₂O, % by mass, Min | 85.0 | 90.0 | 85.0 | IS 1288 : 1982 |
| Cl as NaCl, % by mass, Max | 0.10 | - | 0.10 | IS 1288 : 1982 |
| pH of 10% aqueous suspension, Min | 5.0 | 5 |
Frequently Asked
According to IS 12679:1989 Clause 3.1 Table 1, the maximum allowable impurities in by-product gypsum are:
| Impurity | Phospho-Gypsum | Fluoro-Gypsum | Marine Gypsum |
|---|---|---|---|
| P₂O₅ (%) max | 0.40 | - | - |
| F (%) max | 0.40 | 1.0 | - |
| Na₂O (%) max | 0.10 | - | - |
| K₂O (%) max | 0.20 | - | - |
| Organic matter (%) max | 0.15 | - | - |
| Cl as NaCl (%) max | 0.10 | - | 0.10 |
| CaSO₄·2H₂O (%) min | 85.0 | 90.0 | 85.0 |
| pH (10% suspension) min | 5.0 | 5.0 | 6.0 |
Note: If impurities exceed these limits, the gypsum must be processed to reduce impurities.
This ensures gypsum quality suitable for plaster, blocks, and boards manufacturing.
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According to IS 12679, sample selection and testing for conformity should follow these key steps:
Summary Table for Sample Size (Example):
| Lot Size (Packages) | Number of Packages to Sample |
|---|---|
| Up to 50 | 2 |
| 51 to 100 | 3 |
| Above 100 | 5 |
(Refer to Table 2 of IS 12679 for exact values)
This ensures statistically valid, unbiased quality assessment of the lot.
According to IS 12679, Clause 5.1, by-product gypsum packages must be suitably packed and marked legibly with the following information:
This ensures traceability and quality assurance. Additionally, if the product carries the BIS Standard Mark, it confirms compliance with the standard under BIS supervision.
| Information to Mark | Details |
|---|---|
| Material Name | By-product gypsum |
| Manufacturer Name | Name of manufacturer |
| Date of Manufacture | Clear date on package |
This marking helps in identification, quality control, and regulatory compliance during storage and transport.
IS 12679 covers three types of by-product gypsum:
| Characteristic | Phospho-gypsum | Fluoro-gypsum | Marine gypsum |
|---|---|---|---|
| P2O5, % max | 0.40 | Not specified | Not specified |
| F (Fluoride), % max | 0.40 | 1.0 | Not specified |
| Na2O, % max | 0.10 | Not specified | Not specified |
| K2O, % max | 0.20 | Not specified | Not specified |
| Organic matter, % max | 0.15 | Not specified | Not specified |
| CaSO4·2H2O, % min | 85.0 | 90.0 | 85.0 |
| Cl as NaCl, % max | 0.10 | Not specified | 0.10 |
| pH (10% suspension), min | 5.0 | 5.0 | 6.0 |
This ensures suitability for plaster, blocks, and boards production.
Environmental Considerations for Using Phosphogypsum as per IS 12679
| Characteristic | Max/Min Value |
|---|---|
| P2O5 | 0.40% max |
| Fluoride (F) | 0.40% max |
| Organic matter | 0.15% max |
| CaSO4·2H2O | 85.0% min |
| pH (10% suspension) | 5.0 min |
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In essence, IS 12679 mandates strict chemical limits and processing to mitigate environmental hazards before phosphogypsum use.
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