IS 10013 Part 11981AI Search Enabled✦ AI Generated

water-soluble type wood preservatives, Part 1: Acid-copper-chrome (ACC) preservative

IS 10013 Part 1 (1981) specifies the requirements for Acid-Copper-Chrome (ACC) preservative, a water-soluble fixed type wood preservative used for treating timber and lignocellulosic materials. This standard defines the composition, quality parameters, sampling, and marking requirements to ensure effective preservation and enhanced durability of timber, especially for species of lesser natural durability. It is essential for manufacturers, quality controllers, and engineers involved in timber treatment and wood preservation.

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36Clauses Indexed
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1981Edition
TimberCategory
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What This Standard Covers

IS 10013 Part 1 (1981) specifies the requirements for Acid-Copper-Chrome (ACC) preservative, a water-soluble fixed type wood preservative used for treating timber and lignocellulosic materials. This standard defines the composition, quality parameters, sampling, and marking requirements to ensure effective preservation and enhanced durability of timber, especially for species of lesser natural durability. It is essential for manufacturers, quality controllers, and engineers involved in timber treatment and wood preservation.

Who Uses This Standard

  • Wood Preservation Specialists
  • Timber Treatment Plant Operators
  • Quality Control Engineers in Wood Industry
  • Civil and Structural Engineers
  • Forest Conservators and Officers
  • Manufacturers of Wood Preservatives
  • Research and Development Professionals in Wood Science

Key Topics Covered

Composition and formulation of ACC preservative
Quality and purity requirements of chemicals
Physical forms of preservative (solid, paste, solution)
Sampling procedures for chemical analysis
Chemical analysis methods and active ingredient limits
pH value requirements for preservative solutions
Marking and labeling of preservative containers
Standards for moisture content and active compounds
Application scope for timber and lignocellulosic materials
Compliance with Indian and international practices
Packaging and container specifications
Use of ISI certification mark and quality assurance

Table of Contents

1Scope

IS 10013 Part 1 - Scope Summary & Key Specifications

Scope (from IS 10013 Part 1 - 1981):

  • Specifies requirements for Acid-Copper-Chrome (ACC) preservative, a water-soluble (fixed) type wood preservative.
  • Intended to augment durability of less durable timbers by preservative treatment.
  • Aligns with IS 401-1981 (Code of Practice for Timber Preservation).
  • Emphasizes quality of preservative for effective absorption and penetration.
  • Supports economic utilization of timber resources.

Key Specifications

Active Ingredients (Nominal % by weight)ChemicalContent
Chromic acetate / boric acidCr (C2H3O2)3.H2O5%
Copper sulphateCuSO4.5H2O50%
Sodium dichromate or Potassium dichromateNa2Cr2O7.2H2O or K2Cr2O745%

Units (SI System Used)

QuantityUnitSymbol
Lengthmetrem
Masskilogramkg
Timeseconds
ForcenewtonN
Pressure/StresspascalPa
EnergyjouleJ

Notes:

  • ISI Certification Mark may be used under ISI rules.
  • Results/tests rounded as per IS 2-1960.
  • Scope covers preservative formulation and quality control for timber treatment.

flowchart TD
    A[Timber] --> B[Preservative Treatment]
    B --> C[Acid-Copper-Chrome (ACC) Preservative]
    C --> D[Improved Durability]
    D --> E[Extended Service Life]

Summary: IS 10013 Part 1 defines the formulation and quality requirements of ACC preservative for wood, ensuring enhanced timber durability through standardized chemical composition and treatment processes.

2Composition and Properties of Preservative

IS 10013 (Part 1) – Composition & Properties of Acid-Copper-Chrome Preservative

1. Composition (Nominal proportions by weight)

IngredientChemical FormulaPercentage (%)
Chromic acetate/boric acidCr(C2H3O2)3·H2O5
Copper sulphateCuSO4·5H2O50
Sodium dichromate ORNa2Cr2O7·2H2O45
Potassium dichromateK2Cr2O745

2. Specifications

  • Minimum percentage of each ingredient must not be less than above proportions (Clause 2.1.1).
  • Quality and sampling procedures are per TS: 2753 (Part I) - 1964.
  • Analysis methods for copper, chromium, arsenic, etc., are detailed in IS 10013 Part 1.

3. Notes

  • The preservative is an acid-copper-chrome (ACC) formulation widely used for timber treatment.
  • Proper chemical analysis ensures effective wood preservation and compliance with standards.
flowchart LR
    A[Chromic acetate/Boric acid 5%] --> C[Preservative Mix]
    B[Copper sulphate 50%] --> C
    D[Sodium or Potassium dichromate 45%] --> C
    C --> E[Acid-Copper-Chrome Preservative]

This formulation ensures fungicidal and insecticidal protection for treated timber as per IS 10013 (Part 1).

3Sampling

IS 10013 Part 1 - Sampling Key Points

  1. Sampling Procedure (Clause 3.1):

    • Samples must be taken from a requisite number of drums from a single supply batch.
    • Follow random sampling methods as per IS 4905-1968.
  2. Chemical Analysis (Clause 4.1):

    • Analyze preservative solution ingredients according to IS 2753 (Part 1)-1964.
    • Ensure chemical proportions comply with Clauses 2.1 and 2.1.1 of IS 10013.
  3. Marking (Clause 5.1.1):

    • Containers may bear the ISI Certification Mark, indicating compliance with IS standards and quality control.

Sampling Summary Table

AspectStandard/ClauseDescription
Sampling MethodIS 4905-1968Random sampling from drums
Chemical AnalysisIS 2753 (Part 1)-1964Estimation of preservatives (Cu, As, Cr, Zn, B, creosote, fuel oil)
ComplianceIS 10013 Clauses 2.1, 2.1.1Chemical proportions must meet specified limits
MarkingClause 5.1.1ISI Mark for certified products

Important Notes:

  • Sampling ensures representative quality check of preservative solutions.
  • Chemical estimation methods are standardized for accuracy.
  • ISI Mark guarantees product conformity under ISI supervision.
flowchart TD
    A[Supply Batch] --> B[Random Sampling (IS 4905)]
    B --> C[Sample Collection from Drums]
    C --> D[Chemical Analysis (IS 2753)]
    D --> E{Compliance Check}
    E -->|Yes| F[Mark with ISI Certification]
    E -->|No| G[Reject / Reprocess]

This process ensures quality and consistency in preservative solutions per IS 10013 Part 1.

4Chemical Analysis

IS 10013 (Part 1) - Chemical Analysis of Preservative Solution

Key Specifications (Clause 2.1 & 2.1.1)

IngredientCompound FormulaMinimum % by Weight
Chromic acetate/boric acidCr(C₂H₃O₂)₃·H₂O5
Copper sulphateCuSO₄·5H₂O50
Sodium dichromateNa₂Cr₂O₇·2H₂O45 (alternative)
Potassium dichromateK₂Cr₂O₇45 (alternative)
  • The preservative is an acid-copper-chrome formulation.
  • The percentage of each ingredient shall not be less than the values above.
  • Sodium or potassium dichromate can be used interchangeably.

Chemical Analysis Method (Clause 4.1)

  • Follow IS 2753 (Part 1) - 1964, Clause 3.4 for estimation methods.
  • Analysis includes copper, arsenic, chromium, zinc, boron, creosote, and fuel oil.
  • Sampling should be random as per IS 10013 Part 1 guidelines.

Summary of Steps for Chemical Analysis

flowchart TD
    A[Sampling of Preservative Solution] --> B[Prepare Sample as per IS 2753]
    B --> C[Estimate Copper Content]
    B --> D[Estimate Chromium Content]
    B --> E[Estimate Arsenic, Zinc, Boron]
    B --> F[Estimate Creosote & Fuel Oil]
    C --> G[Compare with Minimum %]
    D --> G
    E --> G
    F --> G
    G --> H{Complies with IS 10013?}
    H -->|Yes| I[Accept Batch]
    H -->|No| J[Reject or Reprocess]

Note: Always round off numerical values as per IS 10013 rules before reporting results.

5Marking

Marking Requirements as per IS 10013 Part 1 (Clause 5.1)

Each container must be legibly marked with the following:

  • Manufacturer's name or trade-mark
  • Date of manufacture
  • Percentage of dry active ingredients

Additional Marking Notes (Clause 5.1.1)

  • Containers may also bear the ISI Certification Mark.
  • The ISI Mark assures compliance with the standard, backed by inspection, testing, and quality control by ISI.
  • Use of ISI Mark is regulated under the Indian Standards Institution (Certification Marks) Act.

Summary Table for Marking Information

Marking ItemDescription
Manufacturer's Name/Trade-markIdentifies the producer or brand
Date of ManufactureProduction date for traceability
Percentage of Dry Active IngredientsEnsures minimum preservative content as per IS

Important Notes

  • The percentage of active ingredients must meet or exceed minimum values specified in Clause 2.1.1.
  • Marking must be clear and durable to ensure traceability and quality assurance.

If you need details on minimum percentages of preservatives or rounding rules, please specify.

Popular Questions About IS 10013 Part 1

?What are the specified active ingredients and their proportions in the ACC preservative?

According to IS 10013 Part 1, the Acid-Copper-Chrome (ACC) preservative active ingredients and their nominal proportions by weight are:

IngredientChemical FormulaProportion (%)
Chromic acetate / Boric acid (Cr (C2H3O2)3·H2O)Chromic acetate or boric acid5
Copper sulphateCuSO4·5H2O50
Sodium dichromate or Potassium dichromateNa2Cr2O7·2H2O or K2Cr2O745

Key Points:

  • The total active ingredients sum to 100% by weight.
  • Either sodium dichromate or potassium dichromate can be used for the 45% portion.
  • For dry solids, active ingredient content should be ≥ 95% of the specified formulation.
  • Minimum proportions for each ingredient must not be less than the values above.

This formulation ensures effective timber preservation by combining copper's fungicidal properties with chromium's fixation and boric acid's insecticidal effect.

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?What purity levels are required for the chemicals used in the preservative formulation?

According to IS 10013 Part 1, the purity requirements for chemicals in preservative formulations are:

  • Minimum 95% purity for each chemical used (Clause 2.5).
  • For dry solid preservatives, not less than 95% active ingredients as specified (Clause 2.4).
  • The preservative solution concentration should be 15% by dissolving at least 1 kg preservative (Clause 3.4).

Analysis methods are detailed in TS: 2753 (Part I)-1964 (Clause 1.3).

Summary:

ParameterRequirement
Chemical purity≥ 95%
Active ingredient in dry solid≥ 95%
Solution concentration15% (1 kg preservative in solution)

This ensures effective preservation and compliance with IS standards.

?How should samples be collected and prepared for chemical analysis?

Sampling and Preparation for Chemical Analysis as per IS 10013 Part 1

  • For Solution or Paste (Clause 3.2):

    • Thoroughly mix the contents with a rod.
    • Collect at least 1 kg sample from each drum for analysis.
  • For Dry Powder Form (Clause 3.3):

    • Take a representative sample amounting to not less than 1% of the total contents.
  • Chemical Analysis (Clause 4.1):

    • Conduct analysis as per IS 2753 (Part 1)-1964 methods (Clause 3.4) for components like copper, arsenic, chromium, zinc, boron, creosote, and fuel oil.
    • Ensure proportions comply with specified limits (Clauses 2.1 and 2.1.1).

Summary Table:

FormSampling MethodSample Size
Solution/PasteMix thoroughly, take sample≥ 1 kg per drum
Dry PowderRepresentative sample≥ 1% of total contents
Loading diagram...

This ensures representative sampling for accurate chemical composition verification.

?What pH range must the preservative solution maintain for effective use?

According to IS 10013 Part 1, the pH range for the preservative solution ready for use must be:

  • Not lower than 2.7
  • Not higher than 4.2

This pH is measured using a glass electrode at 15-25°C (Clause 2.3).

Key points:

  • The solution should maintain this acidic range for effective preservation.
  • The preservative concentration for the solution is typically 15% by weight (Clause 3.4).
  • The preservative may be in solid, semi-liquid, or solution form (Clause 2.2).

Maintaining this pH ensures the preservative's chemical stability and effectiveness in protecting timber or other materials against decay.

?What labeling and marking information is mandatory on preservative containers?

According to IS 10013 Part 1, the mandatory labeling on preservative containers includes:

  • Manufacturer's name or trade-mark
  • Date of manufacture
  • Percentage of dry active ingredients
  • Percentage of total active compounds
  • Amount of moisture

Additional points:

  • For dry solid preservatives, the active ingredient content must be at least 95%.
  • Preservatives can be in dry solid, semi-liquid paste, or solution form, but labeling must clearly indicate active ingredient percentages and moisture content.

This ensures clarity on preservative quality and composition for safe and effective use.

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